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  • 研究员
  • 博士生导师
  • 硕士生导师
  • 教师英文名称:Yarong Zheng
  • 教师拼音名称:zhengyarong
  • 电子邮箱:
  • 所在单位:化学系
  • 职务:化学系系主任
  • 学历:研究生(博士)毕业
  • 办公地点:昇华楼301
  • 性别:
  • 学位:博士学位
  • 在职信息:在职
  • 毕业院校:中国科学技术大学
  • 学科:无机化学
    物理化学
    材料学
    应用化学
论文成果
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Black Phosphorous Mediates Surface Charge Redistribution of CoSe2 for Electrochemical H2O2 Production in Acidic Electrolytes
  • 发表刊物:Adv. Mater.
  • 摘要:Electrochemical generation of hydrogen peroxide (H2O2) by two-electron oxygen reduction offers a green method to mitigate the current dependence on the energy-intensive anthraquinone process, promising its on-site applications. Unfortunately, in alkaline environments, H2O2 is not stable and undergoes rapid decomposition. Making H2O2 in acidic electrolytes can prevent its decomposition, but choices of active, stable, and selective electrocatalysts are significantly limited. Here, the selective and efficient two-electron reduction of oxygen toward H2O2 in acid by a composite catalyst that is composed of black phosphorus (BP) nailed chemically on the metallic cobalt diselenide (CoSe2) surface is reported. It is found that this catalyst exhibits a 91% Faradic efficiency for H2O2 product at an overpotential of 300 mV. Moreover, it can mediate oxygen to H2O2 with a high production rate of ≈1530 mg L−1 h−1 cm−2 in a flow-cell reactor. Spectroscopic and computational studies together uncover a BP-induced surface charge redistribution in CoSe2, which leads to a favorable surface electronic structure that weakens the HOO* adsorption, thus enhancing the kinetics toward H2O2 formation.
  • 备注:Ya-Rong Zheng†, ShaoJin Hu†, Xiao-Long Zhang†, Huanxin Ju, Zhenbin Wang, Peng-Ju Tan, Rui Wu, Fei-Yue Gao, Taotao Zhuang, Xiao Zheng, Junfa Zhu, Min-Rui Gao,* and Shu-Hong Yu*
  • 论文类型:期刊论文
  • 卷号:34
  • 期号:43
  • 页面范围:2205414
  • 是否译文:
  • 发表时间:2022-08-30
  • 发布期刊链接:https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.202205414