A biomimetic metal–organic framework with cuboid inner cavities for enantioselective separation
- DOI码:10.1039/D2QI00152G
- 发表刊物:Inorganic Chemistry Frontiers
- 摘要:A chiral metal–organic framework (CMOF) with accessible binding pockets and multiple recognition sites is constructed from a tricarboxylate ligand derived from phenylalanine. The CMOF features a rare structure with cavities encapsulated by a non-coordinated amino-acid moiety. It has been proven to be an efficient and recyclable chiral host, enabling adsorbing and separating racemic alcohols, diols, and epoxides with excellent enantioselectivity.
- 论文类型:期刊论文
- 通讯作者:Zhu Chengfeng* et al.,
- 学科门类:工学
- 文献类型:J
- 卷号:9
- 期号:11
- 页面范围:2683-2690
- 是否译文:否
- 发表时间:2022-04-08
- 收录刊物:SCI
- 发布期刊链接:https://pubs.rsc.org/en/content/articlelanding/2022/qi/d2qi00152g
附件:
Zhu-2022-A biomimetic metal–organic framework.pdf