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Highly polarized luminescence from an AIEE-active luminescent liquid crystalline film

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Abstract:Luminescent liquid crystals (LLCs) have attracted significant interest for organic optoelectronic applications, especially for the generation of linear polarized light. Here, a novel LLC molecule, 2-(4-(nonanealkoxy)phenyl)-3-(4-formamidephenyl)-acrylonitrile (CN-NPFA), is reported, which shows strong fluorescence in the solid state due to the aggregation-induced enhanced emission (AIEE) effect. Moreover, a well-aligned liquid crystalline film using AIEE-active molecules, is obtained using an in-plane electric field with an alignment layer. It exhibits highly polarized luminescence (ρ = 0.74) with a high fluorescence quantum yield. The device is both cheap and easy to fabricate, and has the potential to be used in practical electro-optic applications.

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Date of Publication:2017-08-02