郝文涛  (副教授)

博士生导师 硕士生导师

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所在单位:高分子系

学历:博士研究生毕业

办公地点:升华楼527

性别:男

联系方式:材料学,材料工程

主要任职:Teaching & Researching

毕业院校:中国科学技术大学

   
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Superhydrophobic and breathable polydimethylsiloxane/ nano-SiO2@polylactic acid electrospun membrane with core-sheath fiber structure

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影响因子:6.5

DOI码:10.1016/j.porgcoat.2023.108126

发表刊物:Progress in Organic Coatings

摘要:Polylactic acid (PLA) has great potential to replace traditional petroleum-based polymers, especially in membrane production, due to its biocompatibility, degradability, and renewability. However, there are rare reports of superhydrophobic and breathable PLA membranes. In this work, a multifunctional PDMS/SiO2@PLA membrane with superhydrophobicity and breathability was prepared by coaxial electrospinning method to coat the surface of PLA fiber with a thin layer of biocompatible polydimethylsiloxane (PDMS) and nano-silica particles. The prepared membrane has a water contact angle (WCA) of 151.8 ± 1.3◦ and a water sliding angle (WSA) of 5.7 ± 0.3◦. Thanks to its superhydrophobicity, it can support a water column of 195 cm. The membrane has excellent breathability that its water vapor transmission rate is ~14.7 kg⋅m-2⋅24 h-1. Moreover, the freezing time of the membrane is 2.25 times longer than that of the original PLA membrane. In addition, it has an oil-water separation efficiency of 99.9 % and a flux of ~12,300 L⋅m-2⋅h-1. The overall performance of this multi-functional PDMS/SiO2@PLA membrane is one of the best among the fluorine-free electrospun membranes.

论文类型:期刊论文

学科门类:工学

文献类型:J

卷号:187

页面范围:108126

是否译文:

发表时间:2023-12-08

收录刊物:SCI

发布期刊链接:https://www.sciencedirect.com/science/article/pii/S0300944023007221

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